GOST 31696-2012

INTERSTATE STANDARD

COSMETIC, HYGIENIC, WASHING PRODUCTS

General technical conditions

Cosmetic hygienic washing products. General specifications

MKS 71.100.70

Date of introduction 2013-07-01

Preface

Preface

The goals, basic principles and general rules for carrying out work on interstate standardization are established by GOST 1.0 "Interstate standardization system. Basic provisions" and GOST 1.2 "Interstate standardization system. Interstate standards, rules and recommendations for interstate standardization. Rules for development, adoption, updating and cancellation"

Standard information

1 PREPARED by the Working Group with the participation of members of the Technical Committee for Standardization TC 360 "Perfume and Cosmetic Products" and with the assistance of the Russian Perfume and Cosmetic Association

2 INTRODUCED by the Federal Agency for Technical Regulation and Metrology

3 ADOPTED by the Interstate Council for Standardization, Metrology and Certification (protocol dated November 15, 2012 N 42)

(Amendment. IUS No. 6-2019).

4 interstate standard GOST 31696-2012 came into force as a national standard of the Russian Federation on July 1, 2013.

5 This standard has been prepared based on the application of GOST R 52345-2005*
________________
* By order of the Federal Agency for Technical Regulation and Metrology of November 29, 2012 N 1762-st GOST R 52345-2005 was canceled from February 15, 2015.

6 INTRODUCED FOR THE FIRST TIME

7 REPUBLICATION. April 2019


Information on the entry into force (termination) of this standard and amendments to it on the territory of the above states is published in the indexes of national standards published in these states, as well as on the Internet on the websites of the relevant national standardization bodies.

In case of revision, change or cancellation of this standard, the relevant information will be published on the official website of the Interstate Council for Standardization, Metrology and Certification in the catalog "Interstate Standards"


An amendment has been made, published in IUS No. 6, 2019

Amendment made by database manufacturer

1 area of ​​use

This standard applies to washing hygienic cosmetic products - shampoos, liquid soap, washing gels (shower, bath, intimate hygiene), cleansing products (foams, gels, mousses), bath foam (hereinafter - washing products), for hygienic hair and skin care products and other products similar in purpose that meet the requirements of this standard.

The standard does not apply to solid toilet soaps and cosmetic liquids.

Safety requirements are set out in 3.1.3 (pH), 3.1.4, 3.2 and section 4, labeling requirements are in 3.3.

2 Normative references

This standard uses normative references to the following interstate standards:

GOST 8.579 State system for ensuring the uniformity of measurements. Requirements for the quantity of packaged goods in packages of any type during their production, packaging, sale and import

GOST 14618.1-78 Essential oils, fragrant substances and intermediate products of their synthesis. Methods for determining chlorine

GOST 22567.1 Synthetic detergents. Methods for determining foaming ability

GOST 26878 Shampoos for hair care and baths. Methods for determining chloride content

GOST 26927 Raw materials and food products. Mercury determination method

GOST 26929-94 Raw materials and food products. Sample preparation Mineralization to determine the content of toxic elements

GOST 26930 Raw materials and food products. Arsenic determination method

GOST 26932 Raw materials and food products. Lead determination methods

GOST 27429 Liquid perfume and cosmetic products. Packaging, labeling, transportation and storage

GOST 28303 Perfume and cosmetic products. Packaging, labeling, transportation and storage

GOST 29188.0-91 * Perfume and cosmetic products. Acceptance rules, sampling, organoleptic test methods
________________
* GOST 29188.0-2014 “Perfume and cosmetic products. Acceptance rules, sampling, methods of organoleptic tests” is in effect.


GOST 29188.2 Perfume and cosmetic products. Method for determining pH value

GOST 30178 Raw materials and food products. Atomic absorption method for determining toxic elements

GOST 31676 Perfume and cosmetic products. Colorimetric methods for determining mass fractions of mercury, lead, arsenic, cadmium

Note - When using this standard, it is advisable to check the validity of reference standards and classifiers on the official website of the Interstate Council for Standardization, Metrology and Certification (www.easc.by) or according to the indexes of national standards published in the states specified in the preface, or on official websites of the relevant national standardization bodies. If an undated reference is given to a document, then the current document should be used, taking into account all changes made to it. If a referenced document to which a dated reference is given is replaced, the specified version of that document should be used. If, after the adoption of this standard, a change is made to the referenced document to which a dated reference is made that affects the referenced provision, that provision shall apply without regard to that change. If a document is canceled without replacement, then the provision in which a reference to it is given applies to the part that does not affect this reference.

3 Technical requirements

3.1 Characteristics

3.1.1 Detergent products are aqueous solutions, gels, emulsions based on surfactants. It may include fragrances, dyes and special additives that improve the consumer properties of the product. All ingredients must be approved for use in the territory of the state that has adopted the standard.

3.1.2 Detergent products must be manufactured in accordance with the requirements of this standard according to recipes, technical requirements and technological regulations (instructions) in compliance with regulatory documents in force in the territory of the states that have adopted the standard.

3.1.3 In terms of organoleptic and physico-chemical indicators, washing products must comply with the requirements and standards specified in Table 1. The value of indicators for a specific product must be given in the technical requirements.

Table 1

3.1.4 Mass fractions of lead, arsenic, mercury and microbiological indicators of washing products should not exceed the standards established or regulatory documents of the states that have adopted the standard.

3.2 Requirements for raw materials and supplies

Raw materials and supplies for the manufacture of washing products must meet the requirements approved in or in the regulatory documents of the states that have adopted the standard.

3.3 Marking

Labeling of consumer containers with cleaning products - according to or according to the regulatory documents of the states that have adopted the standard.

Marking of transport containers is in accordance with GOST 27429 and GOST 28303.

3.4 Packaging

Packaging of washing products - in accordance with GOST 27429 or GOST 28303.

The permissible negative deviation in weight or volume of washing products in consumer packaging must comply with GOST 8.579.

4 Safety requirements

4.1 According to toxicological safety indicators, washing products are classified as hazard class 4 (low-hazard substances) in accordance with or with the regulatory documents of the states that have adopted the standard.

Detergent products should not have a general toxic, skin irritating or sensitizing effect.

4.2 The safety indicators of washing products must not exceed the standards established in or in the regulatory documents of the states that have adopted the standard.

4.3 The list of substances prohibited for use in the production of detergent products is indicated in or in the regulatory documents of the states that have adopted the standard.

4.4 Washing products are fire and explosion proof.

5 Acceptance rules

5.1 Washing products are accepted in accordance with GOST 29188.0-91, section 1.

5.2 Sampling of washing products - according to GOST 29188.0-91, section 2.

Sampling to determine microbiological indicators - according to the regulatory documents of the states that have acceded to the standard.

5.3 To check the compliance of washing products with the requirements of this standard, acceptance and periodic tests are carried out.

5.4 Acceptance tests are carried out according to the following indicators: appearance, color, smell, pH value.

5.5 The procedure and frequency of monitoring for indicators: foaming ability, mass fractions of chlorides and the amount of heavy metals, as well as for microbiological indicators, is established by the manufacturer in the production control program.

6 Test methods

From the sample selected in accordance with GOST 29188.0-91, section 2, a combined sample of washing products is compiled, the mass of which must be at least 100 g. To determine microbiological indicators, the mass of the combined sample must be at least 15 g (cm) according to 3.1.3.

6.1 Definition of appearance

The appearance of washing products is determined according to GOST 29188.0-91, section 3.

6.2 Color definition

The color of washing products is determined by Determination of microbiological indicators - according to regulatory documents of states that have adopted the standard. MKS 71.100.70

Key words: surfactant-based detergent products, shampoos, washing gel, liquid soap, bubble bath, cleaning products, scope of application, links, technical requirements, safety requirements, acceptance rules, test methods, transportation, storage

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Applies to washing hygienic cosmetic products - shampoos, liquid soap, washing gels (shower, bath, intimate hygiene), cleansing products (foams, gels, mousses), bath foam for hygienic hair and skin care.

The standard does not apply to solid toilet soaps and cosmetic liquids.

Edition (January 2006) with Amendment IUS 11-2005

Action completed 02/15/2015

1 area of ​​use

3 Technical requirements

3.1 Characteristics

3.3 Marking

3.4 Packaging

4 Safety requirements

5 Acceptance rules

6 Test methods

6.1 Definition of appearance

6.2 Color definition

6.3 Odor detection

6.5 Determination of foaming ability

6.8 Determination of microbiological parameters

This GOST is located in:

Organizations:

Cosmetic hygienic washing products. General specifications

Normative references

• GOST 12.1.007-76 System of occupational safety standards. Harmful substances. Classification and general safety requirements
• GOST R 1.0-92 State standardization system of the Russian Federation. Basic provisions. Replaced by GOST R 1.0-2004.
• GOST R 1.2-92 State standardization system of the Russian Federation. The procedure for developing state standards. Replaced by GOST R 1.2-2004.
• GOST 14618.1-78 Essential oils, fragrant substances and intermediate products of their synthesis. Methods for determining chlorine
• GOST 22567.1-77 Synthetic detergents. Method for determining foaming ability
• GOST 26878-86 Shampoos for hair care and baths. Method for determining chloride content
• GOST 26927-86
• GOST 26929-94 Raw materials and food products. Sample preparation Mineralization to determine the content of toxic elements
• GOST 26930-86 Raw materials and food products. Arsenic determination method
• GOST 26932-86 Raw materials and food products. Lead determination methods
• GOST 27429-87 Perfume and cosmetic products, liquid. Packaging, labeling, transportation and storage
• GOST 28303-89 Perfumery and cosmetic products. Packaging, labeling, transportation and storage
• GOST 29188.0-91 Perfumery and cosmetic products. Acceptance rules, sampling, methods of organoleptic tests. Replaced by GOST 29188.0-2014.
• GOST 29188.2-91 Cosmetic products. Method for determining the hydrogen index, pH. Replaced by GOST 29188.2-2014.
• GOST 30178-96 Raw materials and food products. Atomic absorption method for determining toxic elements
• GOST R 51301-99 Food products and food raw materials. Stripping voltammetric methods for determining the content of toxic elements (cadmium, lead, copper and zinc)
• GOST R 51391-99 Perfumery and cosmetic products. Information for the consumer. General requirements
• GOST R 51962-2002 Food products and food raw materials. Stripping voltammetric method for determining the mass concentration of arsenic
• GOST 8.579-2002 State system for ensuring the uniformity of measurements. Requirements for the quantity of packaged goods in packages of any type during their production, packaging, sale and import
• SanPiN 1.2.681-97 Hygienic requirements for the production and safety of perfumery and cosmetic products
• GOST R 52621-2006
• Technical Regulations of the Customs Union 009/2011 for Decision 799

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FEDERAL AGENCY

ON TECHNICAL REGULATION AND METROLOGY

Preface

The tasks, basic principles and rules for carrying out work on national standardization in the Russian Federation are established by GOST R 1.0-92 “State standardization system of the Russian Federation. Basic provisions" and GOST R 1.2-92 "State standardization system of the Russian Federation. The procedure for developing state standards"

Standard information

1 DEVELOPED by a working group with the participation of members of the Technical Committee for Standardization TC 360 “Perfume and Cosmetic Products” and with the assistance of the Russian Perfume and Cosmetic Association

2 INTRODUCED by the Technical Committee for Standardization TC 360 “Perfume and cosmetic products”

3 APPROVED AND ENTERED INTO EFFECT by Order of the Federal Agency for Technical Regulation and Metrology dated May 31, 2005 No. 134-st

4 This standard is harmonized in terms of the requirements of Article 4, paragraph 1 paragraph a) of Directive 76/768/EEC of July 27, 1976, as amended 1 - 7

5 INTRODUCED FOR THE FIRST TIME

6 EDITION (January 2006) with Amendment IUS 11-2005

Information about changes to this standard is published in the “National Standards” index, and the text of these changes is published in the “National Standards” information indexes. In case of revision or cancellation of this standard, the relevant information will be published in the information index “National Standards”

NATIONAL STANDARD OF THE RUSSIAN FEDERATION

Date of introduction - 2006-07-01

1 area of ​​use

This standard applies to washing hygienic cosmetic products - shampoos, liquid soap, washing gels (shower, bath, intimate hygiene), cleansing products (foams, gels, mousses), bath foam (hereinafter referred to as washing products) for hygienic care for hair and skin and other products similar in purpose that meet the requirements of this standard.

The standard does not apply to solid toilet soaps and cosmetic liquids.

Safety requirements are set out in 3.1.3 (pH), 3.1.4, 3.2 and section 4, labeling requirements are in 3.3.

2 Normative references

Note - When using this standard, it is advisable to check the validity of the reference standards using the “National Standards” index compiled as of January 1 of the current year, and according to the corresponding information indexes published in the current year. If the reference standard is replaced (changed), then when using this standard you should be guided by the replaced (changed) standard. If the reference standard is canceled without replacement, then the provision in which a reference is made to it is applied in the part that does not affect this reference.

3 Technical requirements

3.1 Characteristics

3.1.1 Detergent products are aqueous solutions, gels, emulsions based on surfactants. They may contain fragrances, dyes and special additives that improve the consumer properties of products. All ingredients must be approved for use in accordance with.

3.1.2 Detergent products must be produced in accordance with the requirements of this standard for recipes, technical requirements and technological regulations (instructions) subject to the requirements.

3.1.3 In terms of organoleptic and physico-chemical indicators, washing products must comply with the requirements and standards specified in Table 1. The value of the indicators for a specific product must be given in the technical requirements.

Table 1

3.1.4 Mass fractions of lead, arsenic, mercury and microbiological, toxicological and clinical laboratory parameters of washing products should not exceed the standards established

3.2 Requirements for raw materials and supplies

Raw materials and materials for the manufacture of washing products must meet the requirements established.

3.3 Marking

Labeling of consumer containers with washing products - according to GOST R 51391.

Marking of transport containers is in accordance with GOST 27429, GOST 28303.

3.4 Packaging

Packaging of washing products - according to GOST 27429 or GOST 28303.

The permissible negative deviation in weight or volume of washing products in consumer packaging must comply with GOST 8.579 (Appendix A).

4 Safety requirements

4.1 According to toxicological safety indicators, detergent products are classified as hazard class 4 (low-hazard substances) in accordance with GOST 12.1.007.

Detergent products should not have a general toxic, skin irritating or sensitizing effect.

4.2 Safety indicators of washing products should not exceed the standards established.

4.3 The list of substances prohibited for use in the production of washing products is indicated.

4.3, 4.3 (Changed edition, Amendment No. 1, Amendment).

4.4 Detergent products are fire and explosion proof.

5 Acceptance rules

5.1 Detergent products are accepted in accordance with GOST 29188.0, section 1.

5.2 Sampling of washing products - according to GOST 29188.0, section. 2.

Sampling to determine microbiological parameters - according to.

5.3 To check the compliance of washing products with the requirements of this standard, acceptance and periodic tests are carried out.

5.4 Acceptance tests are carried out according to the following indicators: appearance, color, smell, pH value.

5.5 The procedure and frequency of monitoring for indicators: foaming ability, mass fractions of chlorides and the amount of heavy metals, as well as for microbiological indicators, is established by the manufacturer in the production control program.

6 Test methods

6.8 Determination of microbiological parameters

Determination of microbiological parameters of washing products is carried out according to.

6.9 Determination of toxicological and clinical laboratory indicators - according to the methods outlined in

TP CU 009/2011 “On the safety of perfumery and cosmetic products” is in force SanPiN 1.2.681-97 Hygienic requirements for the production and safety of perfumery and cosmetic products

MUK 4.2.801-99

Methods of microbiological control of perfumery and cosmetic products

MUK 4.1.1512-03

Stripping voltammetric measurements of the concentration of mercury ions in water

Appendix No. 8.16

Method of quantitative chemical analysis of samples of cosmetic preparations for the content of trace amounts of mercury using stripping voltammetry

Keywords: surfactant-based detergent products, shampoos, washing gel, liquid soap, bubble bath, cleaning products, scope of application, links, technical requirements, safety requirements, acceptance rules, test methods, transportation, storage

Put into effect by order of the Federal Agency for Technical Regulation and Metrology dated November 29, 2012 N 1762-st

Interstate standard GOST 31696-2012

"COSMETIC, HYGIENIC WASHING PRODUCTS. GENERAL TECHNICAL CONDITIONS"

Cosmetic hygienic washing products. General specifications

Preface

The goals, basic principles and basic procedure for carrying out work on interstate standardization are established by GOST 1.0-92 "Interstate standardization system. Basic provisions" and GOST 1.2-2009 "Interstate standardization system. Interstate standards, rules and recommendations for interstate standardization. Rules for development, adoption, application, renewal and cancellation"

1 area of ​​use

This standard applies to washing hygienic cosmetic products - shampoos, liquid soap, washing gels (shower, bath, intimate hygiene), cleansing products (foams, gels, mousses), bath foam (hereinafter - washing products), for hygienic hair and skin care products and other products similar in purpose that meet the requirements of this standard.

The standard does not apply to solid toilet soaps and cosmetic liquids.

Safety requirements are set out in 3.1.3 (pH), 3.1.4, 3.2 and section 4, labeling requirements are in 3.3.

2 Normative references

This standard uses normative references to the following interstate standards:

GOST 8.579-2002 State system for ensuring the uniformity of measurements. Requirements for the quantity of packaged goods in packages of any type during their production, packaging, sale and import

GOST 12.1.007-76 System of occupational safety standards. Harmful substances. Classification and general safety requirements

GOST 14618.1-78 Essential oils, fragrant substances and intermediate products of their synthesis. Methods for determining chlorine

GOST 22567.1-77 Synthetic detergents. Methods for determining foaming ability

GOST 26878-86 Shampoos for hair care and baths. Methods for determining chlorine content

GOST 27429-87 Liquid perfume and cosmetic products. Packaging, labeling, transportation and storage

GOST 28303-89 Perfume and cosmetic products. Packaging, labeling, transportation and storage

GOST 29188.0-91 Perfume and cosmetic products. Acceptance rules, sampling, organoleptic test methods

GOST 29188.2-91 Cosmetic products. Method for determining pH value

GOST 26927-86 Raw materials and food products. Mercury determination method

GOST 26929-86 Raw materials and food products. Sample preparation Mineralization to determine the content of toxic elements

GOST 26930-86 Raw materials and food products. Arsenic determination method

GOST 26932-86 Raw materials and food products. Lead determination methods

GOST 30178-96 Raw materials and food products. Atomic absorption

method for determining toxic elements

GOST 31676-2012 Perfume and cosmetic products. Colorimetric methods for determining mass fractions of mercury, lead, arsenic, cadmium

Note - When using this standard, it is advisable to check the validity of the reference standards using the “National Standards” index compiled as of January 1 of the current year, and according to the corresponding information indexes published in the current year. If the reference standard is replaced (changed), then when using this standard you should be guided by the replacing (changed) standard. If the reference standard is canceled without replacement, then the provision in which a reference is made to it is applied in the part that does not affect this reference.

3 Technical requirements

3.1 Characteristics

3.1.1 Detergent products are aqueous solutions, gels, emulsions based on surfactants. It may include fragrances, dyes and special additives that improve the consumer properties of the product. All ingredients must be approved for use in the territory of the state that has adopted the standard.

3.1.2 Detergent products must be manufactured in accordance with the requirements of this standard according to recipes, technical requirements and technological regulations (instructions) in compliance with regulatory documents in force in the territory of the states that have adopted the standard.

3.1.3 In terms of organoleptic and physico-chemical indicators, washing products must comply with the requirements and standards specified in Table 1. The value of indicators for a specific product must be given in the technical requirements.

Table 1

3.1.4 Mass fractions of lead, arsenic, mercury and microbiological indicators of washing products should not exceed the standards established or regulatory documents of the states that have adopted the standard.

3.2 Requirements for raw materials and supplies

Raw materials and supplies for the manufacture of washing products must meet the requirements approved in or in the regulatory documents of the states that have adopted the standard.

3.3 Marking

Labeling of consumer containers with cleaning products - according to or according to the regulatory documents of the states that have adopted the standard.

Marking of transport containers is in accordance with GOST 27429 and GOST 28303.

3.4 Packaging

Packaging of washing products - in accordance with GOST 27429 or GOST 28303.

The permissible negative deviation in weight or volume of washing products in consumer packaging must comply with GOST 8.579.

4 Safety requirements

4.1 According to toxicological safety indicators, washing products are classified as hazard class 4 (low-hazard substances) in accordance with or with the regulatory documents of the states that have adopted the standard.

Detergent products should not have a general toxic, skin irritating or sensitizing effect.

4.2 The safety indicators of washing products must not exceed the standards established in or in the regulatory documents of the states that have adopted the standard.

4.3 The list of substances prohibited for use in the production of detergent products is indicated in or in the regulatory documents of the states that have adopted the standard.

4.4 Washing products are fire and explosion proof.

5 Acceptance rules

5.1 Washing products are accepted in accordance with GOST 29188.0, section 1.

5.2 Sampling of washing products - according to GOST 29188.0, section 2.

Sampling to determine microbiological indicators - according to the regulatory documents of the states that have acceded to the standard.

5.3 To check the compliance of washing products with the requirements of this standard, acceptance and periodic tests are carried out.

5.4 Acceptance tests are carried out according to the following indicators: appearance, color, smell, pH value.

5.5 The procedure and frequency of monitoring for indicators: foaming ability, mass fractions of chlorides and the amount of heavy metals, as well as for microbiological indicators, is established by the manufacturer in the production control program.

6 Test methods

From the sample selected in accordance with GOST 29188.0, section 2, a combined sample of washing products is compiled, the mass of which must be at least 100 g. To determine microbiological indicators, the mass of the combined sample must be at least 15 g (cm 3) according to 3.1.3.

6.1 Definition of appearance

The appearance of washing products is determined according to GOST 29188.0, section 3.

6.2 Color definition

The color of washing products is determined according to GOST 29188.0, section 3.

6.3 Odor detection

The smell of cleaning products is determined according to GOST 29188.0, section 3.

6.4 Determination of pH value

The pH value is determined according to GOST 29188.2 in an aqueous solution with a mass fraction of detergent products of 10%.

6.5 Determination of foaming ability

Foaming ability is determined according to GOST 22567.1 in an aqueous solution with a mass fraction of detergent products of 0.5%.

6.6 Determination of the mass fraction of chlorides

The mass fraction of chlorides per molar mass of sodium chloride in detergent products is determined according to GOST 26878 or the mass fraction of chlorine - according to section 6 of GOST 14618.1.

6.7 Determination of the mass fraction of lead

The mass fraction of lead is determined according to GOST 31676 or according to GOST 26932 with sample preparation according to GOST 26929 (section 3 or 4).

It is allowed to use the atomic absorption method in accordance with GOST 30178 to determine the mass fraction of lead.

6.7a Determination of the mass fraction of arsenic

The mass fraction of arsenic is determined according to GOST 31676 or according to GOST 26930 with sample preparation according to GOST 26929 (section 3 or 4).

6.7b Determination of the mass fraction of mercury

The mass fraction of mercury is determined according to GOST 31676 or according to GOST 26927 with sample preparation according to GOST 26929 (section 3 or 4).

6.8 Determination of microbiological parameters

Determination of microbiological indicators - according to the regulatory documents of the states that have adopted the standard.

7 Transportation and storage

7.1 Transportation and storage of cleaning products - in accordance with GOST 27429 and GOST 28303.

7.2 The shelf life of each specific washing product is established by the manufacturer.

Bibliography

FEDERAL AGENCY

ON TECHNICAL REGULATION AND METROLOGY

Preface

The tasks, basic principles and rules for carrying out work on national standardization in the Russian Federation are established by GOST R 1.0-92 “State standardization system of the Russian Federation. Basic provisions" and GOST R 1.2-92 "State standardization system of the Russian Federation. The procedure for developing state standards"

Standard information

1 DEVELOPED by a working group with the participation of members of the Technical Committee for Standardization TC 360 “Perfume and Cosmetic Products” and with the assistance of the Russian Perfume and Cosmetic Association

2 INTRODUCED by the Technical Committee for Standardization TC 360 “Perfume and cosmetic products”

3 APPROVED AND ENTERED INTO EFFECT by Order of the Federal Agency for Technical Regulation and Metrology dated May 31, 2005 No. 134-st

4 This standard is harmonized in terms of the requirements of Article 4, paragraph 1 paragraph a) of Directive 76/768/EEC of July 27, 1976, as amended 1 - 7

5 INTRODUCED FOR THE FIRST TIME

6 EDITION (January 2006) with Amendment IUS 11-2005

Information about changes to this standard is published in the “National Standards” index, and the text of these changes is published in the “National Standards” information indexes. In case of revision or cancellation of this standard, the relevant information will be published in the information index “National Standards”

GOST R 52345-2005

NATIONAL STANDARD OF THE RUSSIAN FEDERATION

Date of introduction - 2006-07-01

1 area of ​​use

This standard applies to washing hygienic cosmetic products - shampoos, liquid soap, washing gels (shower, bath, intimate hygiene), cleansing products (foams, gels, mousses), bath foam (hereinafter referred to as washing products) for hygienic care for hair and skin and other products similar in purpose that meet the requirements of this standard.

The standard does not apply to solid toilet soaps and cosmetic liquids.

Requirements ensuring safety are set out in (pH), and in section, labeling requirements - in.

2 Normative references

Note - When using this standard, it is advisable to check the validity of the reference standards using the “National Standards” index, compiled as of January 1 of the current year, and according to the corresponding information indexes published in the current year. If the reference standard is replaced (changed), then when using this standard you should be guided by the replaced (changed) standard. If the reference standard is canceled without replacement, then the provision in which a reference is made to it is applied in the part that does not affect this reference.

3 Technical requirements

3.1 Characteristics

3.1.1 Detergent products are aqueous solutions, gels, emulsions based on surfactants. They may contain fragrances, dyes and special additives that improve the consumer properties of products. All ingredients must be approved for use in accordance with.

3.1.2 Detergent products must be produced in accordance with the requirements of this standard for recipes, technical requirements and technological regulations (instructions) subject to the requirements.

3.1.3 In terms of organoleptic and physico-chemical indicators, washing products must comply with the requirements and standards specified in the table. The value of indicators for a specific product must be given in the technical requirements.

Table 1

3.1.4 Mass fractions of lead, arsenic, mercury and microbiological, toxicological and clinical laboratory parameters of washing products should not exceed the standards established

3.2 Requirements for raw materials and supplies

Raw materials and materials for the manufacture of washing products must meet the requirements established.

3.3 Marking

Labeling of consumer containers with washing products - according to GOST R 51391.

Marking of transport containers is in accordance with GOST 27429, GOST 28303.

3.4 Packaging

Packaging of washing products - according to GOST 27429 or GOST 28303.

The permissible negative deviation in weight or volume of washing products in consumer packaging must comply with GOST 8.579 (Appendix A).

4 Safety requirements

4.1 According to toxicological safety indicators, detergent products are classified as hazard class 4 (low-hazard substances) in accordance with GOST 12.1.007.

Detergent products should not have a general toxic, skin irritating or sensitizing effect.

4.2 Safety indicators of washing products should not exceed the standards established.

4.3 The list of substances prohibited for use in the production of washing products is indicated.

4.3, 4.3 (Changed edition, Amendment No. 1, Amendment).

4.4 Detergent products are fire and explosion proof.

5 Acceptance rules

5.1 Detergent products are accepted in accordance with GOST 29188.0, section 1.

5.2 Sampling of washing products - according to GOST 29188.0, section. 2.

Sampling to determine microbiological parameters - according to.

5.3 To check the compliance of washing products with the requirements of this standard, acceptance and periodic tests are carried out.

5.4 Acceptance tests are carried out according to the following indicators: appearance, color, smell, pH value.

5.5 The procedure and frequency of monitoring for indicators: foaming ability, mass fractions of chlorides and the amount of heavy metals, as well as for microbiological indicators, is established by the manufacturer in the production control program.

6 Test methods

6.1 Definition of appearance

The appearance of washing products is determined according to GOST 29188.0, section 3.

6.2 Color definition

The color of washing products is determined according to GOST 29188.0, section 3.

6.3 Odor detection

The smell of the detergent product is determined according to GOST 29188.0, section 3.

6.4 Determination of pH value

The pH value is determined according to GOST 29188.2 in an aqueous solution with a mass fraction of detergent product of 10%.

6.5 Determination of foaming ability

Foaming ability is determined according to GOST 22567.1 in an aqueous solution with a mass fraction of detergent product of 0.5%.

6.6 Determination of the mass fraction of chlorides

The mass fraction of chlorides per molar mass of sodium chloride in the washing product is determined according to GOST 26878 or the mass fraction of chlorine - according to section 6

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DEVELOPED by the USSR Ministry of Food Industry

A. L. Voitsekhovskaya, A. A. Zelenetskaya, N. N. Kalinina, A. T. Sotnikova INTRODUCED by the Ministry of Food Industry of the USSR

Deputy Minister V. A. Lazko

APPROVED AND ENTERED INTO EFFECT by Resolution of the USSR State Committee on Standards dated April 24, 1986 No. 1061

STATE STANDARD OF THE USSR UNION

(ST SEV 5186-85)

HAIR AND BATH SHAMPOOS

Method for determining chloride content

Shampoos for hair and body. Method for determination of chloride content

By Decree of the USSR State Committee on Standards dated April 24, 1936 N9 1061, the delinquency period was established

from 01.07.86 to 01.07.91

Failure to comply with the standard is punishable by law

This standard applies to liquid shampoos for hair care and bathing. The standard does not apply to coloring, soap and intensely colored shampoos.

The essence of the method is to titrate a sample of the tested shampoo with a solution of silver nitrate in the presence of potassium chromate as an indicator and quantify the chloride content.

The standard fully complies with ST SEV 5186-85.

1. EQUIPMENT. REAGENTS AND SOLUTIONS

Rectified ethyl alcohol - according to GOST 5962-67.

Preparation of titrated solutions and determination of their concentration according to GOST 25794.3 - 83.

2. CONDUCT OF THE TEST

2.1. In a flat-bottomed flask, weigh from 2 to 5 g of the tested shampoo with an error of no more than 0.005 g, dissolve it in 50 cm 3 of water, add 2 drops of methyl red solution. If the solution is yellow in color, then it is neutralized with diluted nitric acid until a pink color appears. Then add 2.5 cm 3 of a solution of potassium chromate and titrate with a solution of silver nitrate until a brown color appears.

3. PROCESSING RESULTS

3.1. The mass fraction of chlorides in a sample of the tested shampoo based on the molecular weight of sodium chloride (X) in percent is calculated using the formula

„ V0.584

d --,

where V is the volume of silver nitrate solution concentration

0.1 mol/dm 3 spent on sample titration, cm 3 ;

t is the mass of the test shampoo sample, g;

0.584 - conversion factor to sodium chloride.

3.2. The test result is taken as the arithmetic mean of the results of three parallel measurements, the permissible differences between which should not exceed 0.1%.

Editor A. A. Zimovnova Technical editor //. V. Belyakova Proofreader V. F. Malyutina

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